Compound Formulation
RUBBER COMPOUNDING
It is a homogeneous mixture of ingredients used in a particular product manufacture such that the properties of most of the ingredients are unchanged in the final product whereby providing a defined set of mechanical properties.
Compounding:
It is the science of selecting and combining elastomers and additives to obtain an intimate mixture that will develop the necessary physical and chemical properties for a finished product.
Rubber compounding is a term covering a wide scope including the art and procedures that are necessary to produce useful products from natural or synthetic elastomers. A competent rubber compounder must be able to use the proper elastomers and additives available to meet the conditions required for the finished product. This requires a thorough understandind of the following:
- Properties of the elastomers available.
- Vulcanizating systems to give the potential properties needed.
- Modifying materials which give the required physical properties and aging resistance.
- Compounds must be able to process properly depending on the processing equipment.
- Commercial compound design.
Comparative Properties of Elastomers:
Carbon Blacks used for Rubber Compounding (Basis of classification):
The average surface area of the carbon black as measured by ‘Nitrogen surface area (NSA)’ divided into 10 arbitrary groups as follows.
Carbon Blacks: Summary of Typical Properties:
Non-Black Fillers: Summary of Typical Properties:
Effect of Fillers on Processing and Vulcanizate Properties of Rubber Compounds:
Estimation of Shore A Hardness of Rubber Compounds:
Procedure: To the base polymer hardness; add/subtract hardness change for each filler or softener.
Typical Properties of Rubber Processing Oils:
Capacities of Mixing Mills:
Capacities of Refiner Mills & Cracker Mills:
Mold Shrinkage calculations for rubber Mold Design:
%Shrinkage = [0.0205-(100-X) M] x ∆T
where,
X = Rubber Content by volume (include oil, factice etc.), ∆T = Difference between curing temperature & room temperature in ºC
M = Constant depending on filler (Usually, 0.00025 – 0.00030)